z-logo
Premium
In Search of Aluminum Hexathiohypodiphosphate: Synthesis and Structures of ht‐AlPS 4 , lt‐AlPS 4 , and Al 4 (P 2 S 6 ) 3
Author(s) -
Kuhn Alexander,
Eger Roland,
Ganter Pirmin,
Duppel Viola,
Nuss Jürgen,
Lotsch Bettina V.
Publication year - 2014
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201400385
Subject(s) - monoclinic crystal system , orthorhombic crystal system , crystallography , tetragonal crystal system , crystal structure , superstructure , group (periodic table) , chemistry , bar (unit) , x ray crystallography , morphology (biology) , diffraction , materials science , physics , geology , paleontology , organic chemistry , meteorology , thermodynamics , optics
Abstract We report the high‐pressure synthesis and the structure of aluminum hexathiohypodiphosphate, Al 4 (P 2 S 6 ) 3 , along with the redetermination of the structures of two modifications of AlPS 4 . Al 4 (P 2 S 6 ) 3 crystallizes in the monoclinic space group C 2 with a = 17.584(3), b = 10.156(2), c = 6.698(1) Å, β = 106.93(1)° in a superstructure of the layered FePS 3 structure type with tripled a axis. Hereby, Al 3+ occupies 2/3 of the Fe 2+ sites in an ordered fashion. The structure model obtained from single‐crystal X‐ray diffraction was corroborated by TEM‐PED. The low‐temperature modification of AlPS 4 with platelet‐like morphology shows tetragonal symmetry [space group P $\bar{4}$ 2 c , a = b = 5.6572(9), c = 9.220(2) Å]. The orthorhombic high‐temperature modification with fibrous needle‐like morphology of AlPS 4 is isotpyic with BPS 4 [space group I 222, a = 5.660(2), b = 5.759(2), c = 9.189(2) Å].

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here