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Impact of Crystal Chemistry upon Spin Orientation Transitions in Magnetic Perovskites
Author(s) -
Raveau Bernard,
Motin Seikh Md.
Publication year - 2014
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201400348
Subject(s) - spin (aerodynamics) , condensed matter physics , manganese , materials science , chromium , cobalt , magnetic anisotropy , doping , octahedron , anisotropy , transition metal , crystal (programming language) , crystallography , orientation (vector space) , crystal structure , magnetic structure , chemical physics , chemistry , inorganic chemistry , magnetic field , magnetization , physics , catalysis , metallurgy , optics , computer science , biochemistry , quantum mechanics , thermodynamics , programming language , mathematics , geometry
The control of the spin orientation transitions in perovskites containing manganese, cobalt, iron, and chromium, based on crystal chemistry factors is reviewed. We describe herein the effect of the size and of the magnetic nature of the Ln 3+ cations and of the doping and large substitutions at the octahedral sites. Spin blockade introduced by nanostructural effects and magnetic anisotropy induced by laser pulse application are also discussed.