Non‐innocent Redox Behavior of Amidinato Ligands: Spectroscopic Evidence for Amidinyl Complexes | Zendy

Ehret Fabian | Zendy; Bubrin Martina | Zendy; Záliš Stanislav | Zendy; Kaim Wolfgang | Zendy

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Non‐innocent Redox Behavior of Amidinato Ligands: Spectroscopic Evidence for Amidinyl Complexes

Author(s) -

Ehret Fabian,

Bubrin Martina,

Záliš Stanislav,

Kaim Wolfgang

Publication year - 2014

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201400306

Subject(s) - electron paramagnetic resonance , chemistry , redox , yield (engineering) , pyridine , metal , medicinal chemistry , stereochemistry , inorganic chemistry , organic chemistry , materials science , physics , nuclear magnetic resonance , metallurgy

The compounds [Ru II (bmaa – )(bpy) 2 ](PF 6 ) [ 1 (PF 6 )], [Ru II (bmaa – )(Cym)Cl] ( 2 ), and [Ru II (bmaa – )(Cym)(py)](PF 6 ) [ 3 (PF 6 )] [bmaa – = N , N ′‐bis(4‐methoxyphenyl)acetamidinato, bpy = 2,2'‐bipyridine, Cym = p ‐cymene, py = pyridine] were studied spectroelectrochemically (EPR, UV/Vis) to reveal metal‐centered oxidation for 1 + but bmaa – ‐based oxidation to yield amidinyl ligands in 2 + and 3 2+ .

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