Premium
Synthesis and Structure of an Arylmanganese(II) 8‐Hydroxyquinolinate Tetranuclear Cluster
Author(s) -
Justyniak Iwona,
Kornowicz Arkadiusz,
Prochowicz Daniel,
Sokołowski Kamil,
Lewiński Janusz
Publication year - 2014
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201400302
Subject(s) - manganese , chemistry , molecule , cluster (spacecraft) , crystallography , intermolecular force , crystal structure , quinolinate , stereochemistry , amino acid , tryptophan , biochemistry , organic chemistry , quinolinic acid , computer science , programming language
Reaction of 8‐hydroxyquinoline with dimesitylmanganese [(Mes) 2 Mn] 3 results in the formation of arylomanganese(II) tetranuclear cluster [(Mes) 2 Mn 4 (q) 6 ] · 4PhMe ( 1 ) supported by the quinolinate ligands. Molecular studies showed that the centrosymmetric molecule of 1 contains two pairs of manganese atoms of different coordination modes formed by association of the two dinuclear [MesMn(q)][Mn(q) 2 ] moieties. A detailed analysis of the crystal structure of 1 revealed that single molecules of 1 self‐assemble through a network of intermolecular CH ar ··· π interactions into closely packed quasi‐grid 2D layers.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom