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A Unique (3,3,4)‐Connected Cd II Coordination Polymer with Dicarboxylate and Imidazole‐Containing Coligands: Synthesis, Crystal Structure, and Luminescent Property
Author(s) -
Jia Huali,
Wang Chunjie,
Guo Feng
Publication year - 2014
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201400294
Subject(s) - luminescence , imidazole , crystal structure , sulfonyl , coordination polymer , crystallography , polymer , dicarboxylic acid , benzene , single crystal , stereochemistry , chemistry , materials science , polymer chemistry , organic chemistry , alkyl , optoelectronics
Abstract The three‐dimensional (3D) coordination polymer {[Cd 2 (4,4′‐sdb) 2 (tib)(H 2 O) 3 ] · H 2 O} n ( 1 ) [4,4′‐H 2 sdb = 4,4′‐sulfonyl‐dicarboxylic acid and tib = 1,3,5,‐tris(1‐imidazolyl) benzene] was prepared by the combination of a V‐shaped 4,4′‐sulfonyl‐dicarboxylic acid and neutral organonitrogen coligands. The structure of the neutral polymeric complex 1 was determined by single‐crystal X‐ray diffraction studies. Complex 1 exhibits a twofold interpenetrated (3,3,4)‐connected 3D architecture with the point symbol (6.8 2 ).(6 4 .8 2 ).(8 3 ). In addition, the luminescent property of complex 1 was investigated.