A Unique (3,3,4)‐Connected Cd II  Coordination Polymer with Dicarboxylate and Imidazole‐Containing Coligands: Synthesis, Crystal Structure, and Luminescent Property | Zendy

Jia Huali | Zendy; Wang Chunjie | Zendy; Guo Feng | Zendy

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A Unique (3,3,4)‐Connected Cd II Coordination Polymer with Dicarboxylate and Imidazole‐Containing Coligands: Synthesis, Crystal Structure, and Luminescent Property

Author(s) -

Jia Huali,

Wang Chunjie,

Guo Feng

Publication year - 2014

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201400294

Subject(s) - luminescence , imidazole , crystal structure , sulfonyl , coordination polymer , crystallography , polymer , dicarboxylic acid , benzene , single crystal , stereochemistry , chemistry , materials science , polymer chemistry , organic chemistry , alkyl , optoelectronics

The three‐dimensional (3D) coordination polymer {[Cd 2 (4,4′‐sdb) 2 (tib)(H 2 O) 3 ] · H 2 O} n ( 1 ) [4,4′‐H 2 sdb = 4,4′‐sulfonyl‐dicarboxylic acid and tib = 1,3,5,‐tris(1‐imidazolyl) benzene] was prepared by the combination of a V‐shaped 4,4′‐sulfonyl‐dicarboxylic acid and neutral organonitrogen coligands. The structure of the neutral polymeric complex 1 was determined by single‐crystal X‐ray diffraction studies. Complex 1 exhibits a twofold interpenetrated (3,3,4)‐connected 3D architecture with the point symbol (6.8 2 ).(6 4 .8 2 ).(8 3 ). In addition, the luminescent property of complex 1 was investigated.

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