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Formation of a Stannyl Amido Complex by the Reaction of a Terminal Iridium Nitrido Complex with a Stannane
Author(s) -
Sieh Daniel,
Burger Peter
Publication year - 2015
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201400235
Subject(s) - iridium , stannane , chemistry , hydride , reactivity (psychology) , ligand (biochemistry) , tin , transition metal , terminal (telecommunication) , medicinal chemistry , metal , stereochemistry , photochemistry , organic chemistry , catalysis , medicine , telecommunications , biochemistry , alternative medicine , receptor , pathology , computer science
The chemistry of low valent late transition metal complexes with a terminal nitrido unit still is a growing field and only few reactions have been studied so far. We have tested the reactivity of a pseudo square planar iridium nitrido complex against triphenyl tin hydride, which results in a highly water sensitive stannyl amido complex, which is an unprecedented example of a transition metal complex with a terminal N(H)–SnR 3 ligand.
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