Syntheses, Crystal Structures, and Luminescent Properties of Two Cadmium(II) Complexes with CdS Network and (3,4)‐Connected Topology | Zendy

Liu Lu | Zendy; Zhang Zhiwei | Zendy; Zhao Zhiling | Zendy; Niu Shaoli | Zendy; Song Aijun | Zendy; Peng Youshun | Zendy

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Syntheses, Crystal Structures, and Luminescent Properties of Two Cadmium(II) Complexes with CdS Network and (3,4)‐Connected Topology

Author(s) -

Liu Lu,

Zhang Zhiwei,

Zhao Zhiling,

Niu Shaoli,

Song Aijun,

Peng Youshun

Publication year - 2014

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201400188

Subject(s) - luminescence , cadmium , benzene , crystallography , elemental analysis , single crystal , topology (electrical circuits) , crystal structure , infrared spectroscopy , chemistry , solid state , materials science , inorganic chemistry , organic chemistry , optoelectronics , mathematics , combinatorics

Two cadmium(II) complexes with different dicarboxylate ligands, [Cd(ADC)(bib) 0.5 ] ( 1 ) and [Cd(HIDC)(bib) 0.5 ] n ( 2 ) [H 2 ADC = 1,3‐adamantanedicarboxylic acid, H 3 IDC = 4,5‐imidazoledicarboxylate and bib = 1,4‐bis(1‐imidazolyl) benzene] were obtained. Complexes 1 and 2 were characterized by single‐crystal and powder X‐ray diffraction, FT‐IR spectroscopy, and elemental analysis. The complexes showed different topological nets. Furthermore, the luminescent properties of complexes 1 and 2 were investigated in the solid state at room temperature.

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