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[B(O–C 6 H 4 –CN) 4 ] – based Silver and Copper Coordination Polymers
Author(s) -
Lund Henrik,
Harloff Jörg,
Schulz Axel,
Villinger Alexander
Publication year - 2014
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201400150
Subject(s) - chemistry , denticity , coordination polymer , copper , metathesis , reactivity (psychology) , salt (chemistry) , octane , crystallography , polymer , crystal structure , ligand (biochemistry) , medicinal chemistry , polymerization , organic chemistry , medicine , alternative medicine , pathology , biochemistry , receptor
A series of new coordination polymers bearing the [B(O–C 6 H 4 –CN) 4 ] – anion was synthesized. Two new, one dimensional coordination frameworks of the type M [B(O–C 6 H 4 –CN) 4 ] ( M = Ag, Cu) were obtained by salt metathesis. The reactivity towards organic Lewis‐bases was studied. The reaction with bidentate ligands yielded two dimensional networks with the general formula [ M (L)][B(O–C 6 H 4 –CN) 4 ] {L = 2,2′‐bipyridine, 4,4′‐bipyridine, 1,2‐bis(pyridyl)ethane, 1,4‐diazabicyclo[2.2.2]octane}. The synthesis, properties and single crystal structure are reported.