The Structure of Bis(dimethyldithioarsinato)gallium(III) Sulfide [(Me 2 AsS 2 ) 2 Ga] 2 S·0.75H 2 O: A Hydrolysis Product of (Me 2 AsS 2 ) 3 Ga that Contains a Bridging Sulfide and both Pendant and Bridging Dimethyldithioarsinato Ligands | Zendy

Papatriantafyllopoulou Constantina | Zendy; Nastopoulos Vassilios | Zendy; Ioannou Panayiotis V. | Zendy

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The Structure of Bis(dimethyldithioarsinato)gallium(III) Sulfide [(Me 2 AsS 2 ) 2 Ga] 2 S·0.75H 2 O: A Hydrolysis Product of (Me 2 AsS 2 ) 3 Ga that Contains a Bridging Sulfide and both Pendant and Bridging Dimethyldithioarsinato Ligands

Author(s) -

Papatriantafyllopoulou Constantina,

Nastopoulos Vassilios,

Ioannou Panayiotis V.

Publication year - 2014

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201400076

Subject(s) - gallium , crystallography , molecule , hydrolysis , crystallization , zigzag , crystal structure , product (mathematics) , hydrogen bond , chemistry , sulfide , materials science , stereochemistry , organic chemistry , mathematics , geometry

The complex (Me 2 AsS 2 ) 3 Ga ( 1 ) attracted water molecules that slowly and completely hydrolyzed it. The product was the dinuclear gallium compound (Me 2 AsS 2 ) 2 Ga–S–Ga(S 2 AsMe 2 ) 2 ( 2 ) as 2· 0.75H 2 O, which was structurally characterized with X‐ray crystallography ( P 2 1 2 1 2 1 , R 1 = 0.0321, wR 2 = 0.0622). Compound 2 shows an approximate non‐crystallographic twofold axis. The packing in the crystalline state is dictated by the mediation of crystallization water molecules, which connect the complex units through strong O–H ··· S and weak C–H ··· O hydrogen bonds into infinite zigzag chains.

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