Contributions to the Chemistry of the Cyclopentadienyl Complex [Cp∧RuCl 2 ] 2  (“Cp‐roof” = η 5 ‐1‐Methoxy‐2,4‐ tert ‐butyl‐3‐neopentylcyclopentadienyl) | Zendy

Risse Julie | Zendy; Dutta Barnali | Zendy; Solari Euro | Zendy; Scopelliti Rosario | Zendy; Severin Kay | Zendy

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Contributions to the Chemistry of the Cyclopentadienyl Complex [Cp∧RuCl 2 ] 2 (“Cp‐roof” = η 5 ‐1‐Methoxy‐2,4‐ tert ‐butyl‐3‐neopentylcyclopentadienyl)

Author(s) -

Risse Julie,

Dutta Barnali,

Solari Euro,

Scopelliti Rosario,

Severin Kay

Publication year - 2014

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201400048

Subject(s) - cyclopentadienyl complex , bimetallic strip , carbene , ruthenium , chemistry , phosphine , ligand (biochemistry) , steric effects , reactivity (psychology) , stereochemistry , medicinal chemistry , organic chemistry , catalysis , medicine , biochemistry , receptor , alternative medicine , pathology

The dimeric ruthenium complex [Cp∧RuCl 2 ] 2 is easily accessible in a one‐pot reaction from RuCl 3 (solv) n and tert ‐butylacetylene. It features sterically very demanding “Cp‐roof” ligands (Cp∧ = η 5 ‐1‐methoxy‐2,4‐ tert ‐butyl‐3‐neopentylcyclopentadienyl), which impart a unique reactivity. Herein we describe the synthesis and the characterization of novel Cp∧Ru complexes bearing a bridging carbene ligand, a linear imido ligand, or an orthometalated phosphine ligand. Furthermore, the microwave‐assisted syntheses of the bimetallic complexes [Cp∧Ru(μ‐Cl) 3 Ru( p ‐cymene)] and [Cp∧Ru(μ‐Cl) 3 RhCp*] are described.

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