A Three‐dimensional Homochiral Camphorate Coordination Polymer Based on Two Types of Dinuclear Cadmium Clusters and a Flexible Bis(benzimidazole)‐based Ligand | Zendy

Zhang JuWen | Zendy; Kan XiaoMin | Zendy; Li XiaoHui | Zendy; Gong ChunHua | Zendy; Tian AiXiang | Zendy; Wang XiuLi | Zendy

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A Three‐dimensional Homochiral Camphorate Coordination Polymer Based on Two Types of Dinuclear Cadmium Clusters and a Flexible Bis(benzimidazole)‐based Ligand

Author(s) -

Zhang JuWen,

Kan XiaoMin,

Li XiaoHui,

Gong ChunHua,

Tian AiXiang,

Wang XiuLi

Publication year - 2014

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201400019

Subject(s) - benzimidazole , ligand (biochemistry) , cadmium , coordination polymer , metal , polymer , photoluminescence , crystallography , chemistry , stereochemistry , materials science , topology (electrical circuits) , crystal structure , organic chemistry , receptor , optoelectronics , mathematics , biochemistry , combinatorics

A three‐dimensional (3D) homochiral metal‐organic coordination polymer with a 6‐connected 4 12 .6 3 topology was synthesized hydrothermally, Cd 4 (D‐cam) 4 (bbbm) 2 ( 1 ) [D‐H 2 cam = D‐(+)‐camphoric acid and bbbm = 1,1‐(1,4‐butanediyl)bis‐1 H ‐benzimidazole], which represents the first example of metal‐camphorate coordination polymers constructed from two types of dinuclear cadmium clusters [Cd 2 (O 2 C–) 4 ] and a flexible bis(benzimidazole)‐based ligand. The thermal and photoluminescent properties of 1 were investigated.

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