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A Manganese(II) Coordination Polymer with the Ligands Azide and Picolinate: Synthesis, Structure, and Magnetic Properties
Author(s) -
Yang Qian,
Liu SuiJun,
Zhang YingHui
Publication year - 2014
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201400016
Subject(s) - picolinic acid , azide , manganese , antiferromagnetism , elemental analysis , coordination polymer , chemistry , infrared spectroscopy , polymer , crystallography , powder diffraction , inorganic chemistry , crystal structure , polymer chemistry , organic chemistry , physics , condensed matter physics
The two dimensional Mn II coordination polymer [Mn 3 (pic) 2 (N 3 ) 4 (CH 3 OH)] n ( 1 ) with the ligands azide and picolinic acid (Hpic) was synthesized and characterized by IR spectroscopy, elemental analysis, and powder and single‐crystal X‐ray diffraction analysis. Meanwhile, analysis of the magnetic properties revealed antiferromagnetic exchange for polymer 1 .