Microwave‐assisted Synthesis, Structure, and Properties of a Heptanuclear Cobalt Cluster with 2‐Ethyliminomethyl‐6‐methoxy‐phenol | Zendy

Huang QiuPing | Zendy; Li Gui | Zendy; Zhang HaiYang | Zendy; Zhang ShuHua | Zendy; Li HePing | Zendy

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Microwave‐assisted Synthesis, Structure, and Properties of a Heptanuclear Cobalt Cluster with 2‐Ethyliminomethyl‐6‐methoxy‐phenol

Author(s) -

Huang QiuPing,

Li Gui,

Zhang HaiYang,

Zhang ShuHua,

Li HePing

Publication year - 2014

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201400009

Subject(s) - ethylamine , cobalt , acetonitrile , phenol , chemistry , solvent , benzaldehyde , elemental analysis , cluster (spacecraft) , methanol , infrared spectroscopy , crystallography , single crystal , crystal structure , alkoxy group , powder diffraction , inorganic chemistry , nuclear chemistry , organic chemistry , catalysis , computer science , programming language , alkyl

The heptanuclear cobalt cluster [Co 7 (emmp) 6 (CH 3 O) 6 ] · (ClO 4 ) 2 ( 1 ) (Hemmp = 2‐ethyliminomethyl‐6‐methoxy‐phenol) was synthesized by the microwave‐assisted reaction of Co(ClO 4 ) 2 · 6H 2 O with 3‐ethoxy‐2‐hydroxy‐benzaldehyde (Hehb) and ethylamine in mixed solvent (acetonitrile:methanol = 1:1). Complex 1 was characterized by IR spectroscopy, elemental analysis, and X‐ray single‐crystal diffraction. The magnetic properties of 1 are discussed. Complex 1 displays dominant ferromagnetic interactions from the nature of the binding modes through μ 3 ‐OCH 3 and μ 2 ‐phenoxo.

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