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Is the Volume‐Based Thermodynamics (VBT) Approach Valid for the Estimation of the Lattice Enthalpy of Salts Containing the 5, 5′‐(Tetrazolate‐1 N ‐oxide) Dianion?
Author(s) -
Glasser Leslie,
Jenkins H. Donald B.,
Klapötke Thomas M.
Publication year - 2014
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201400007
Subject(s) - lattice energy , enthalpy , oxide , ionic bonding , thermodynamics , standard enthalpy of formation , ion , chemistry , lattice (music) , standard enthalpy change of formation , inorganic chemistry , crystal structure , crystallography , physics , organic chemistry , acoustics
In previous publications we have used volume‐based thermodynamics (VBT) to estimate the lattice energies and enthalpies of new high‐energy ionic materials. The use of the VBT approach for salts containing non‐spherical ions such as the 5, 5′‐(tetrazolate‐1N‐oxide) dianion in TKX‐50 [bishydroxylammonium 5, 5′‐(tetrazolate‐1N‐oxide)] has received some criticism. Herein we show that the VBT approach is suitable for the estimation of lattice energies/enthalpies for such salts.