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An Unprecedented 5‐Connected Self‐penetrated Cadmium(II) Coordination Polymer: Synthesis, Crystal Structure, and Luminescent Property
Author(s) -
Zhang Shuxin,
Liu Daofu
Publication year - 2014
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201300682
Subject(s) - isophthalic acid , luminescence , crystallography , cadmium , coordination polymer , ligand (biochemistry) , crystal structure , powder diffraction , infrared spectroscopy , materials science , biphenyl , single crystal , chemistry , organic chemistry , biochemistry , receptor , polyester , optoelectronics , terephthalic acid
The Cd II coordination polymer, [Cd(BDC)(L) 1.5 ] ( 1 ) [H 2 BDC = isophthalic acid and L = 1,4‐bis(2‐methylimidazol‐3‐ium‐1‐yl)biphenyl], was synthesized by the assembly of Cd II ion, L ligand, and isophthalic acid, respectively. Complex 1 was characterized by single‐crystal X‐ray diffraction, elemental analyses, FT‐IR spectroscopy, and power X‐ray diffraction (PXRD). X‐ray structural analysis reveals that complex 1 is a 5‐connected self‐penetrated net with point symbol (4 2 .6 8 ). Furthermore, the luminescent property of the title complex is investigated.