Hydrothermal Syntheses, Crystal Structures, and Photoluminescent Properties of Two New Cadmium(II) Coordination Polymers Based on Asymmetric Dicarboxylate and N‐donor Ligands | Zendy

Miao Hui | Zendy; Wang Ying | Zendy; Cui YuMin | Zendy; Liu ZhaoDi | Zendy

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Hydrothermal Syntheses, Crystal Structures, and Photoluminescent Properties of Two New Cadmium(II) Coordination Polymers Based on Asymmetric Dicarboxylate and N‐donor Ligands

Author(s) -

Miao Hui,

Wang Ying,

Cui YuMin,

Liu ZhaoDi

Publication year - 2014

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201300467

Subject(s) - hydrothermal circulation , photoluminescence , ligand (biochemistry) , crystallography , amine gas treating , polymer , coordination polymer , benzoic acid , topology (electrical circuits) , ion , chemistry , cadmium , crystal structure , materials science , stereochemistry , organic chemistry , chemical engineering , receptor , combinatorics , optoelectronics , mathematics , biochemistry , engineering

Two new coordination polymers, {[Cd 2 (cpb) 2 (bpa)(H 2 O)] · H 2 O}( 1 ) and {[Cd 2 (bda) 2 (bpa) 2 ] · 3H 2 O} ( 2 ) [H 2 cpb = 2‐(3′‐carboxyphenoxy) benzoic and H 2 bda = 2, 4'‐biphenyldicarboxylic acid; bpa = bis(4‐pyridyl)amine], were obtained from hydrothermal reactions of Cd 2+ ion with two asymmetric dicarboxylic acids and N‐donor ligand, respectively. Complex 1 features a two‐dimensional (2D) 5‐connected SnS topological net with Schläfli symbol (4 8 .6 2 ). Complex 2 also shows a 2D structure with 4‐connected sql topology with Schläfli symbol (4 4 .6 2 ). Furthermore, the photoluminescent properties of 1 and 2 were investigated.

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