A Practical and Inexpensive One‐Pot Synthesis of Bis(indenyl)dimethyltitanium with Aqueous Workup Procedure | Zendy

Ross Jan H. | Zendy; Preuß Till | Zendy; Brahms Christian | Zendy; Doye Sven | Zendy

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A Practical and Inexpensive One‐Pot Synthesis of Bis(indenyl)dimethyltitanium with Aqueous Workup Procedure

Author(s) -

Ross Jan H.,

Preuß Till,

Brahms Christian,

Doye Sven

Publication year - 2014

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201300433

Subject(s) - methyllithium , titanium tetrachloride , cyclopentadiene , tetrachloride , aqueous solution , indene , chemistry , titanium , organic chemistry , catalysis , tin

A simple, reliable, and reproducible procedure for the multi‐gram synthesis of highly pure bis(indenyl)dimethyltitanium is presented. The procedure relies on a one‐pot conversion of inexpensive indene, methyllithium, and titanium tetrachloride to [Ind 2 TiMe 2 ] and a convenient and quick aqueous workup protocol. Overall, quantities of several grams of [Ind 2 TiMe 2 ] can be synthesized within a few hours. The procedure can also be used for the synthesis of [Cp 2 TiMe 2 ] from cyclopentadiene, methyllithium, and titanium tetrachloride.

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