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Utilizing a Metal Melt of Gallium for the Synthesis of the Homoleptic 1, 2,4‐Triazolate Dense Framework 3 ∞ [Ga(Tz) 3 ]
Author(s) -
Rybak JensChristoph,
Rekawka Adam,
MüllerBuschbaum Klaus
Publication year - 2013
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201300401
Subject(s) - homoleptic , gallium , chemistry , metal , thermal stability , crystallography , topology (electrical circuits) , materials science , organic chemistry , mathematics , combinatorics
The low melting element gallium was utilized as a metal melt together with the azole 1, 2,4,‐ 1H ‐triazole for the synthesis of the homoleptic framework 3 ∞ [Ga(Tz) 3 ], Tz – = 1, 2,4‐triazolate. The framework is formed at 180 °C at the phase border of two liquid phases, gallium and the azole, which do not mix with one another. Thus, 1, 2,4,‐ 1H ‐triazole is also in molten state. The homoleptic triazolate adopts the CoAs 3 structure and a (4, 6) net topology, exhibiting good thermal stability of 440 °C.