Premium
Synthesis, Structure, and Luminescent Property of the Templated Borate [C 9 H 14 N]·[B 5 O 6 (OH) 4 ]
Author(s) -
Pan ChunYang,
Zhong LiJuan,
Lu Jing,
Li DaGuang,
Zhao FengHua,
Yang HongMei
Publication year - 2014
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201300387
Subject(s) - triclinic crystal system , luminescence , thermogravimetric analysis , crystallography , differential thermal analysis , infrared spectroscopy , fourier transform infrared spectroscopy , powder diffraction , boron , hydrogen bond , x ray crystallography , hydrothermal synthesis , materials science , single crystal , crystal structure , spectroscopy , analytical chemistry (journal) , chemistry , hydrothermal circulation , diffraction , molecule , organic chemistry , physics , optoelectronics , quantum mechanics , seismology , optics , geology
The templated borate, [C 9 H 14 N] · [B 5 O 6 (OH) 4 ], was synthesized under hydrothermal conditions. Single crystal X‐ray diffraction techonology reveals that it crystallizes in the triclinic system, space group P $\bar{1}$ (No. 2). The material was also characterized by element analysis, Fourier transform infrared spectroscopy (FTIR), powder X‐ray diffraction (PXRD), thermogravimetric and differential thermal analysis (TG‐DTA), and luminescence spectroscopy. The compound consisted of isolated pentaborate [B 5 O 6 (OH) 4 ] – and N ‐butylpyridinium cations [C 9 H 14 N] + . The [B 5 O 6 (OH) 4 ] – anions are connected together by hydrogen bonds to form a three‐dimensional framework, in which [C 9 H 14 N] + cations are located in. [C 9 H 14 N] · [B 5 O 6 (OH) 4 ] exhibits tunable luminescence emission at 415–458 nm by means of heating treatment from 100 to 300 °C.