Synthesis, X‐ray Studies, and Catalytic Efficacy of a Novel Iron Complex Containing an N,O‐Type Bidentate Thiazoline Ligand | Zendy

Amini Mojtaba | Zendy; Bigdeli Mina | Zendy; DelsouzHafshejani Sepideh | Zendy; Ellern Arkady | Zendy; Woo L. Keith | Zendy

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Synthesis, X‐ray Studies, and Catalytic Efficacy of a Novel Iron Complex Containing an N,O‐Type Bidentate Thiazoline Ligand

Author(s) -

Amini Mojtaba,

Bigdeli Mina,

DelsouzHafshejani Sepideh,

Ellern Arkady,

Woo L. Keith

Publication year - 2014

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201300302

Subject(s) - denticity , thiazoline , ligand (biochemistry) , chemistry , reactivity (psychology) , crystal structure , hydrogen peroxide , catalysis , crystallography , x ray , medicinal chemistry , stereochemistry , organic chemistry , medicine , biochemistry , physics , receptor , alternative medicine , pathology , quantum mechanics

The reactions of FeCl 3 · 6H 2 O and 2‐(2′‐hydroxyphenyl)‐2‐thiazoline as a bidentate O‐N donor thiazoline ligand (thoz) afford a five‐coordinate Fe III complex [Fe(thoz) 2 Cl] with a distorted square pyramidal configuration. Complex [Fe(thoz) 2 Cl] was isolated as air‐stable crystalline solids and fully characterized, including by single‐crystal X‐ray structure analysis. Complex [Fe(thoz) 2 Cl] shows very efficient reactivity in the oxidation of sulfides to their corresponding sulfoxides using urea hydrogen peroxide (UHP) as the oxidant at room temperature in air.

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