An Oxygen/Chlorine Double‐Capped Praseodymium Tetramer Cluster Complex with Thiazole | Zendy

Dannenbauer Nicole | Zendy; MüllerBuschbaum Klaus | Zendy

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An Oxygen/Chlorine Double‐Capped Praseodymium Tetramer Cluster Complex with Thiazole

Author(s) -

Dannenbauer Nicole,

MüllerBuschbaum Klaus

Publication year - 2013

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201300263

Subject(s) - tetramer , thiazole , chemistry , crystallography , cluster (spacecraft) , chloride , hydroxide , anhydrous , praseodymium , inorganic chemistry , stereochemistry , organic chemistry , enzyme , computer science , programming language

A tetramer cluster complex of the formula [Pr 4 Cl 10 (OH) 2 (thz) 8 (H 2 O) 2 ] was prepared constituted by two edge sharing metal triangles coordinated by thiazole (thz) and chloride ligands bent together by opposing μ 3 ‐hydroxide and chloride capping for both triangles. The tetramer is the first thiazole complex of a lanthanide ion and shows a previously unknown symmetric capping mode. It co‐crystallizes with an anhydrous dimeric complex of the formula [Pr 2 Cl 6 (thz) 8 ] in equal amounts.

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