CsNaC 2 , CsKC 2 , CsRbC 2  – Syntheses and Crystal Structures of Three New Acetylides | Zendy

Liebig Stefan | Zendy; Paulus Michael | Zendy; Sternemann Christian | Zendy; Ruschewitz Uwe | Zendy

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CsNaC 2 , CsKC 2 , CsRbC 2 – Syntheses and Crystal Structures of Three New Acetylides

Author(s) -

Liebig Stefan,

Paulus Michael,

Sternemann Christian,

Ruschewitz Uwe

Publication year - 2013

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201300147

Subject(s) - alkali metal , crystallography , chemistry , synchrotron , crystal structure , metal , type (biology) , structure type , materials science , organic chemistry , physics , optics , ecology , biology

Three new alkali metal acetylides CsNaC 2 , CsKC 2 , and CsRbC 2 have been synthesized and characterized by means of synchrotron powder diffraction studies. As a new synthetic approach, the binary alkali metal acetylides were reacted at relatively low temperatures (200 °C). DSC measurements were performed to prove the general usability of this reaction. CsKC 2 and CsRbC 2 crystallize in a variant of the anti ‐PbCl 2 ‐type structure ( P nma, Z = 4), while for CsNaC 2 a new structure type ( P bcm, Z = 4) is found.

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