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Halogen Bonding in the Assembly of a 1D Cadmium(II) Polymer Based on Chlorendic Acid (HET)
Author(s) -
Cui PeiPei,
Cui LunFeng,
Zhang LiangLiang,
Sun DaoFeng
Publication year - 2013
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201300141
Subject(s) - hydrogen bond , halogen , supramolecular chemistry , polymer , thermal stability , halogen bond , luminescence , cadmium , coordination polymer , metal , crystallography , chemistry , crystal structure , materials science , polymer chemistry , molecule , organic chemistry , alkyl , optoelectronics
A new complex based on chlorendic acid (HET), [Cd 8 (HET) 8 (DMF) 4 (H 2 O) 12 ] · 8DMF ( 1 ) was synthesized by liquid evaporate method from the mixture of HET and Cd(NO 3 ) 2 · 4H 2 O. Single crystal X‐ray analysis reveals that the structure of complex 1 features a one‐dimensional (1D) wave chain that is further assembled into three‐dimensional (3D) framework directed by supramolecular interactions, including hydrogen bond, Cl ··· Cl halogen bond, and so on. To the best of our knowledge, this is the first metal‐organic coordination polymer based on chlorendic acid (HET). The luminescent property and thermal stability of complex 1 were also discussed.