Premium
Synthesis, Structure, and Characterization of a Microporous Metal‐Organic Framework with PtS Topology
Author(s) -
Zhang QingFeng,
Luo JunHua,
Yuan AiHua
Publication year - 2013
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201300117
Subject(s) - sbus , microporous material , topology (electrical circuits) , metal organic framework , tetrahedron , materials science , characterization (materials science) , excitation , crystallography , chemistry , nanotechnology , physics , composite material , mathematics , combinatorics , adsorption , quantum mechanics
The microporous metal‐organic framework Cd 2 (ABTC)(H 2 O)(DMA) 2 · H 2 O · 3DMA ( 1 ) (H 4 ABTC = 3, 3′,5, 5′‐azobenzenetetracarboxylic acid; DMA = N , N ′‐dimethylacetamide) was prepared by solvothermal reaction and characterized. X‐ray structure analysis revealed that compound 1 is a three‐dimensional (3D) open framework with 2D channels. The topology is based on a PtS net, constructed of 4‐connected rectangular ABTC 4– units with 4‐connected tetrahedral dinuclear Cd 2 (CO 2 ) 4 (H 2 O)(DMA) 2 secondary building units (SBUs). The solid‐state excitation‐emission spectra showed that the strongest emission peak is at 403 nm upon excitation at λ = 287 nm.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom