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Synthesis, Structures, and Luminescent Properties of two 3, 5‐Dimethyl‐1‐H‐1, 2,4‐triazole‐Based Zinc Metal‐Organic Frameworks with Aromatic Carboxylate as Coligand
Author(s) -
Huang Yao,
Liu LongJiang,
Zhou MingShan,
Zhou XiaoJun,
Zhu Chao,
Fu FeiE,
Zhang YongMing
Publication year - 2013
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201300068
Subject(s) - carboxylate , zinc , luminescence , chemistry , hydrothermal circulation , crystal structure , metal organic framework , metal , 1,2,4 triazole , photoluminescence , single crystal , inorganic chemistry , crystallography , materials science , stereochemistry , medicinal chemistry , organic chemistry , chemical engineering , optoelectronics , adsorption , engineering
Two metal‐organic frameworks, [Zn(dmtrz)(btrc) 1/3 ] n ( 1 ) and [Zn 2 (dmtrz) 2 (btec)(H 2 O) 2 ] n ( 2 ) (dmtrz = 3, 5‐dimethyl‐1‐H‐1, 2,4‐triazole, btrc = 1, 3,5‐benzenetricarboxylate, btec = 1, 2,4, 5‐benzenetetracarboxylate), were synthesized by hydrothermal reaction. The crystal structure analysis reveals that compound 1 is a dense 3D framework with Schläfli symbols of {4 3 } 2 {4 6 · 6 6 · 8 3 } 3 , which is a loh1 structure. Compound 2 is a 2D network. In addition, the photoluminescence of two compounds were studied in solid state at room temperature, together with their thermal analysis.