Introducing a New Naphthoxime‐based Ligand into the Chemistry of Triangular [Mn 3 ] Complexes | Zendy

Hołyńska Małgorzata | Zendy; Frank Nicolas | Zendy; Dehnen Stefanie | Zendy

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Introducing a New Naphthoxime‐based Ligand into the Chemistry of Triangular [Mn 3 ] Complexes

Author(s) -

Hołyńska Małgorzata,

Frank Nicolas,

Dehnen Stefanie

Publication year - 2012

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201200454

Subject(s) - chemistry , manganese , supramolecular chemistry , crystallography , ligand (biochemistry) , oxime , antiferromagnetism , hydrogen bond , ion , crystal structure , stereochemistry , inorganic chemistry , molecule , medicinal chemistry , organic chemistry , biochemistry , physics , receptor , condensed matter physics

A new type of naphthoxime‐based ligand, 1‐(1‐hydroxynaphthalen‐2‐yl)ethanone oxime (naphthsaoH 2 , 1a ), is introduced into the chemistry of manganese(III) complexes. First triangular [Mn 3 ] compound with this ligand is presented: [Mn 3 O(naphthsao) 3 (CH 3 OH) 5 (CH 2 ClCOO)] ( 1 ). Also preliminary structural studies for [Mn 3 O(naphthsao) 3 (CH 3 OH) 5 (CH 3 COO)] ( A ) and 0.52[Mn 3 O(naphthsao) 3 (CH 3 OH) 5 (H 2 O)] · 0.48[Mn 3 O(naphthsao) 3 (CH 3 OH) 6 ] ( B ) are mentioned. Compound 1 was characterized by X‐ray diffraction studies and by a preliminary investigation of the magnetic properties, showing antiferromagnetic coupling of the Mn III ions. Compound 1 displays a supramolecular motif of hydrogen‐bonded chains.

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