A Luminescent Cage‐Like Complex Constructed by Bidentate Pyridine‐Containing Ligand and Silver Nitrate | Zendy

Liu Ying | Zendy; Yu YingHui | Zendy; Liu YiFu | Zendy; Hou GuangFeng | Zendy; Wang XiaoDan | Zendy; Wen Bo | Zendy; Gao JinSheng | Zendy

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A Luminescent Cage‐Like Complex Constructed by Bidentate Pyridine‐Containing Ligand and Silver Nitrate

Author(s) -

Liu Ying,

Yu YingHui,

Liu YiFu,

Hou GuangFeng,

Wang XiaoDan,

Wen Bo,

Gao JinSheng

Publication year - 2013

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201200344

Subject(s) - luminescence , denticity , pyridine , chemistry , benzene , cage , nitrate , ligand (biochemistry) , silver nitrate , photochemistry , crystal structure , crystallography , inorganic chemistry , materials science , nuclear chemistry , organic chemistry , receptor , biochemistry , mathematics , optoelectronics , combinatorics

The cage‐like complex, Ag 4 L 4 (NO 3 ) 4 ( 1 ) [L = 1, 4‐bis(pyridine‐2‐ylmethoxy)benzene] was synthesized by the reaction of the flexible bidentate ligand and silver nitrate. It was characterized by elemental analysis, IR spectroscopy, TG, and single‐crystal X‐ray analysis. Complex 1 is reported as the first cage‐like cluster constructed by four nitrate anions bridging two [2+2] macrocycles. A blue luminescent emission and luminescent enhancement effect are observed in complex 1 .

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