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A Luminescent Cage‐Like Complex Constructed by Bidentate Pyridine‐Containing Ligand and Silver Nitrate
Author(s) -
Liu Ying,
Yu YingHui,
Liu YiFu,
Hou GuangFeng,
Wang XiaoDan,
Wen Bo,
Gao JinSheng
Publication year - 2013
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201200344
Subject(s) - luminescence , denticity , pyridine , chemistry , benzene , cage , nitrate , ligand (biochemistry) , silver nitrate , photochemistry , crystal structure , crystallography , inorganic chemistry , materials science , nuclear chemistry , organic chemistry , receptor , biochemistry , mathematics , optoelectronics , combinatorics
The cage‐like complex, Ag 4 L 4 (NO 3 ) 4 ( 1 ) [L = 1, 4‐bis(pyridine‐2‐ylmethoxy)benzene] was synthesized by the reaction of the flexible bidentate ligand and silver nitrate. It was characterized by elemental analysis, IR spectroscopy, TG, and single‐crystal X‐ray analysis. Complex 1 is reported as the first cage‐like cluster constructed by four nitrate anions bridging two [2+2] macrocycles. A blue luminescent emission and luminescent enhancement effect are observed in complex 1 .