Alternative Synthesis and Structures of  C ‐monoacetylenic Phosphaalkenes | Zendy

Orthaber Andreas | Zendy; Öberg Elisabet | Zendy; Jane Reuben T. | Zendy; Ott Sascha | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Alternative Synthesis and Structures of C ‐monoacetylenic Phosphaalkenes

Author(s) -

Orthaber Andreas,

Öberg Elisabet,

Jane Reuben T.,

Ott Sascha

Publication year - 2012

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201200324

Subject(s) - isomerization , sonogashira coupling , acetylene , chemistry , stereochemistry , crystallography , catalysis , palladium , organic chemistry

An alternative synthesis of C ‐monoacetylenic phosphaalkenes trans ‐Mes*P=C(Me)(C≡CR) (Mes* = 2, 4, 6‐ t Bu 3 Ph, R = Ph, SiMe 3 ) from C ‐bromophosphaalkenes cis ‐Mes*P=C(Me)Br using standard Sonogashira coupling conditions is described. Crystallographic studies confirm cis ‐ trans isomerization of the P=C double bond during Pd‐catalyzed cross coupling, leading exclusively to trans ‐acetylenic phosphaalkenes. Crystallographic studies of all synthesized compounds reveal the extend of π‐conjugation over the acetylene and P=C π‐systems.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research