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On the Reaction of Triphenylphosphane with Thionyl Chloride
Author(s) -
Klein HansFriedrich,
Kuhn Annette,
Kuhn Norbert,
Laufer Stefan,
Ströbele Markus
Publication year - 2012
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201200287
Subject(s) - thionyl chloride , chemistry , crystal structure , triphenylphosphine , medicinal chemistry , chloride , polymer chemistry , crystallography , organic chemistry , catalysis
Triphenylphosphine reacts with thionyl chloride to give [Ph 3 PCl]Cl, Ph 3 PO and Ph 3 PS the formation of the anions S(O)Cl and SCl being discussed; the crystal structure of [Ph 3 PCl]Cl · S(O)Cl 2 is reported.
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