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Three New Lanthanide Coordination Polymers Built from H 2 bpdc Ligands: Syntheses, Structures, and Properties
Author(s) -
Sun YaGuang,
Lv TianYi,
Gao Xin,
Xiong Gang,
Sun Di,
He LingLing,
Xu ZhenHe,
Wang ShuJu,
Ding Fu
Publication year - 2012
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201200226
Subject(s) - isostructural , lanthanide , crystallography , hydrothermal synthesis , elemental analysis , materials science , infrared spectroscopy , powder diffraction , coordination polymer , hydrothermal circulation , metal organic framework , crystal structure , polymer , single crystal , chemistry , inorganic chemistry , organic chemistry , chemical engineering , ion , composite material , engineering , adsorption
Abstract Three new lanthanide‐organic coordination polymers, {[ Ln 2 (bpdc) 2 (H 2 O) 6 (NO 3 )] · NO 3 } [ Ln = La ( 1 ), Ce ( 2 ), Pr ( 3 )] (H 2 bpdc = 2, 2′‐bipyridine‐6, 6′‐dicarboxylic acid) were synthesized under hydrothermal conditions and structurally characterized by elemental analysis, IR spectroscopy as well as single‐crystal and powder X‐ray diffraction. Single‐crystal X‐ray diffraction analysis revealed that compounds 1 – 3 are isostructural, composed of two dimensional honeycomb network linked by bpdc ligands. The magnetic property of compound 3 was investigated.