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Lead Fluoridooxidovanadates(V), Pb(V 2 O 2 F 8 ), Pb(VOF 5 ), and Mixed Valent Fluoridooxidovanadate(IV, V), Pb 3 F(V 4 O 3 F 18 )
Author(s) -
Lozinšek Matic,
Goreshnik Evgeny,
Žemva Boris
Publication year - 2012
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201200176
Subject(s) - vanadium , anhydrous , chemistry , raman spectroscopy , crystallography , analytical chemistry (journal) , inorganic chemistry , physics , environmental chemistry , organic chemistry , optics
The lead fluoridooxidovanadates(V), Pb(V 2 O 2 F 8 ) and Pb(VOF 5 ), were synthesized from PbF 2 and VOF 3 in anhydrous HF. Their crystal structures were determined and Raman spectra recorded. Compound Pb 3 F(V 4 O 3 F 18 ) with a novel mixed valent vanadium(IV, V) fluoridooxido anion, V 4 O 3 F 18 5– , obtained as a by‐product, was also structurally characterized.