[VO(dien)] 2 GeS 4 : Solvothermal Synthesis and Crystal Structure with an  Ortho ‐Thiogermanate as Tetradentate Ligand | Zendy

Wang Jing | Zendy; Näther Christian | Zendy; Djamil John | Zendy; Bensch Wolfgang | Zendy

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[VO(dien)] 2 GeS 4 : Solvothermal Synthesis and Crystal Structure with an Ortho ‐Thiogermanate as Tetradentate Ligand

Author(s) -

Wang Jing,

Näther Christian,

Djamil John,

Bensch Wolfgang

Publication year - 2012

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201200174

Subject(s) - orthorhombic crystal system , ligand (biochemistry) , octahedron , chemistry , crystal structure , crystallography , diethylenetriamine , molecule , hydrogen bond , solvothermal synthesis , ion , sulfur , organic chemistry , receptor , biochemistry

The compound [VO(dien)] 2 GeS 4 ( 1 , dien = diethylenetriamine) features an ortho ‐thiogermanate anion [GeS 4 ] 4– , which acts as tetradentate ligand joining [VO(dien)] 2– complexes. The compound was obtained under solvothermal conditions crystallizing in thenon‐centrosymmetric orthorhombic space group Pna 2 1 with a =19.8310(11), b = 8.0814(5), c = 12.0889(9) Å, V = 1937.4(2) Å 3 and Z = 4. The V 4+ cations are in a distorted octahedral environment of a tridentate dien molecule, one oxygen atom and two sulfur atoms from the [GeS 4 ] 4– anion. A three‐dimensional network is generated by hydrogen bonding interactions.

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