Synthesis, Structure, and Photoluminescent Properties of a New 3D Metal‐Organic Framework with Unusual Ag I  Chains | Zendy

Wang JiJiang | Zendy; Cao PeiXiang | Zendy; Zhang MeiLi | Zendy; Gao LouJun | Zendy; Hou XiangYang | Zendy

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Synthesis, Structure, and Photoluminescent Properties of a New 3D Metal‐Organic Framework with Unusual Ag I Chains

Author(s) -

Wang JiJiang,

Cao PeiXiang,

Zhang MeiLi,

Gao LouJun,

Hou XiangYang

Publication year - 2012

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201200140

Subject(s) - metal organic framework , biphenyl , thermogravimetric analysis , infrared spectroscopy , luminescence , photoluminescence , benzene , gravimetric analysis , single crystal , crystallography , metal , crystal structure , hydrothermal circulation , chemistry , materials science , spectroscopy , infrared , hydrothermal synthesis , chemical engineering , organic chemistry , physics , optoelectronics , adsorption , quantum mechanics , engineering , optics

A new 3D metal‐organic framework {[Ag 4 (btc)(bix) 2 ] · H 2 O} n ( 1 ) [H 4 btc = biphenyl‐2, 2′,4, 4′‐tetracarboxylic acid, bix = 1, 4‐bis(imidazol‐1‐ylmethyl)benzene] was synthesized under hydrothermal conditions and characterized by single‐crystal X‐ray diffraction, infrared (IR) spectroscopy, thermal gravimetric analysis (TGA), and luminescence studies. The most remarkable structural feature of 1 is that the 1D chain and 2D network interpenetrated structures are further linked by parallel aligned 1D Ag I chains to generate 3D metal‐organic framework.

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