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A Copper‐Carboxylate Layer‐Framework with Pseudo‐Kagomé Net
Author(s) -
Wang XiaoFeng,
Zhang XiuLian,
Zhou Xin,
Li Jun,
Kuang YunFei,
Chen JiHao
Publication year - 2012
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201200131
Subject(s) - carboxylate , copper , ferromagnetism , net (polyhedron) , crystallography , coordination polymer , ion , ammonia , chemistry , layer (electronics) , diffraction , materials science , inorganic chemistry , stereochemistry , condensed matter physics , physics , nanotechnology , crystal structure , mathematics , organic chemistry , geometry , optics
A two dimensional coordination polymer with pseudo‐Kagomé net [Cu 3 (btc) 2 (NH 3 ) 8 (H 2 O)] was prepared from Cu(NO 3 ) 2 · 3H 2 O and 1, 3, 5‐benzenetricarboxylic acid (btc) in ammonia aqua solution and was structurally characterized by X‐ray diffraction. The magnetic susceptibility measurements, measured from 2 to 300 K, revealed a weak anti ‐ferromagnetic interaction between the Cu II ions via the btc ligands.