Stabilization of an Intramolecularly Coordinated Stannylidenium Cation | Zendy

Martincová Jana | Zendy; Dostál Libor | Zendy; Růžička Aleš | Zendy; HerresPawlis Sonja | Zendy; Jambor Roman | Zendy

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Stabilization of an Intramolecularly Coordinated Stannylidenium Cation

Author(s) -

Martincová Jana,

Dostál Libor,

Růžička Aleš,

HerresPawlis Sonja,

Jambor Roman

Publication year - 2012

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201200064

Subject(s) - chemistry , crystallography , ion , nuclear magnetic resonance spectroscopy , spectroscopy , diffraction , stereochemistry , physics , organic chemistry , quantum mechanics , optics

The treatment of trans ‐{[2, 6‐(Me 2 NCH 2 ) 2 C 6 H 3 ]SnI} 2 PtI 2 with Na(pyt) (pyt = 2‐mercaptopyridine) yielded the unprecedented complex {{[2, 6‐(Me 2 NCH 2 ) 2 C 6 H 3 ]Sn}Pt(μ‐pyt) 2 I} ( 1 ), where a Sn←N coordinated stannylidenium (LSn II ) + fragment donates a to a [Pt II (pyt) 2 I] – anion. Compound 1 was characterized by NMR spectroscopy and molecular structure was determined by X‐ray diffraction analysis. The bonding situation in 1 was analyzed by DFT studies.

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