Syntheses and Fluorescence Properties of New Coordination Polymers Containing 4, 4′‐Dinitrostilbene‐2, 2′‐Disulfonate Building Unit Supported by Rigid Auxiliary Ligands | Zendy

Ji ShuYing | Zendy; Liu Lu | Zendy; Mu YaJuan | Zendy; Jia YanYuan | Zendy; Hou HongWei | Zendy; Mi LiWei | Zendy

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Syntheses and Fluorescence Properties of New Coordination Polymers Containing 4, 4′‐Dinitrostilbene‐2, 2′‐Disulfonate Building Unit Supported by Rigid Auxiliary Ligands

Author(s) -

Ji ShuYing,

Liu Lu,

Mu YaJuan,

Jia YanYuan,

Hou HongWei,

Mi LiWei

Publication year - 2012

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201200018

Subject(s) - thermogravimetry , elemental analysis , fluorescence , chemistry , crystallography , polymer , infrared spectroscopy , coordination polymer , crystal structure , single crystal , ligand (biochemistry) , inorganic chemistry , organic chemistry , physics , optics , biochemistry , receptor

Two new coordination polymers, [Pb(phen) 2 (dans)] n ( 1 ) and [Pb(4, 4′‐bipy)(dans)] n ( 2 ) (dans = disodium 4, 4′‐dinitrostilbene‐2, 2′‐disulfonate, phen = 1, 10‐phenanthroline and 4, 4′‐bipy = 4, 4′‐bipyridyl) were synthesized and characterized by elemental analysis, thermogravimetry, IR spectroscopy, and X‐ray single crystal diffraction. Compound 1 is a 1D chain with Pb–O bond lengths in the range of 2.76 to 2.90 Å,. The structure of 2 is a three‐dimensional (3D) framework with (4 4 · 6 10 · 8)(3 · 4 3 · 5 2 )(4 3 · 6 3 ) topology.

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