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A 1D → 3D Two‐Fold Interpenetration Array Formed by Hydrogen‐Bonding Interactions
Author(s) -
Ma DeYun,
Guo HaiFu,
Lu Kuan,
Pan Yong,
Qin Liang,
Blatov Vladislav A.
Publication year - 2012
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201100545
Subject(s) - hydrogen bond , cobalt , hydrothermal circulation , biphenyl , chemistry , crystallography , polymer , salt (chemistry) , polymer chemistry , stereochemistry , materials science , inorganic chemistry , chemical engineering , organic chemistry , molecule , engineering
The self‐assembly of 4′‐hydroxy‐biphenyl‐4‐carboxylic acid (H 2 hbc), 4, 4′‐bipyridine (4, 4′‐bpy) with a cobalt salt under hydrothermal conditions yielded a novel dinuclear cobalt(II) coordination polymer, {[Co(Hhbc) 2 (4, 4′‐bpy)] · H 2 O} n ( 1 ), where the coordinating polymeric chains are connected together through hydrogen bonding into a 3D framework of the primitive cubic ( pcu ) topology. Two pcu frameworks are interweaved into a 3D twofold Class Ia interpenetrating array.