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Synthesis and Structural Characterization of a Novel Heterodinuclear Vanadium(IV)‐Nickel(II) Complex
Author(s) -
Du ShiZhen,
Feng Jun,
Cheng YiFeng,
An Lan,
Lu XiaoMing
Publication year - 2012
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201100428
Subject(s) - moiety , nickel , catechol , vanadium , diamine , chemistry , molecule , hydrogen bond , crystallography , polymer chemistry , stereochemistry , inorganic chemistry , organic chemistry
A novel V IV ‐Ni II heterodinuclear complex [VO(cat) 2 ][Ni(1, 2‐PDA) 2 H 2 O] ( 1 ) (cat = catechol; 1, 2‐PDA = 1, 2‐propane diamine) was synthesized at low temperature (10 °C) and characterized by IR spectroscopy and X‐ray diffraction. A novel Ni–O=V structure exists in the complex, the vanadyl–catechol moiety and the nickel–diamine moiety are connected by an oxygen bridge; all molecules are further assembled into crystallites by O–H ··· O hydrogen bonds.