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Assembly of a New 3D Octamolybdate‐based Compound: Using the Flexible Bis(triazole) ligand with a –(CH 2 ) 6 – Spacer
Author(s) -
Tian Aixiang,
Liu Xiaojing,
Liu Guiying,
Ying Jun,
Wang Xiuli
Publication year - 2012
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201100376
Subject(s) - moiety , ligand (biochemistry) , chemistry , thermogravimetric analysis , triazole , crystallography , cyclic voltammetry , 1,2,4 triazole , infrared spectroscopy , stereochemistry , electrochemistry , medicinal chemistry , organic chemistry , electrode , biochemistry , receptor
Through utilizing the flexible bis(triazole) ligand 1, 6‐bis(1, 2, 4‐triazol‐1‐yl)hexane (btx), a new octamolybdate‐based compound, [Cu 2 (btx) 4 (β‐Mo 8 O 26 )] · H 2 O ( 1 ), was synthesized under hydrothermal conditions. It was characterized by single‐crystal X‐ray diffraction, elemental analyses, IR spectroscopy, thermogravimetric analysis, and cyclic voltammetry. In compound 1 , the [β‐Mo 8 O 26 ] 4– anion acts as a bi‐connected inorganic linkage to connect the Cu‐btx moieties. The Cu1‐btx moiety linked by the [β‐Mo 8 O 26 ] 4– anions exhibits a 2D layer, while the Cu2‐btx moiety also shows a similar 2D layer. Furthermore, these two 2D moieties construct a 3D framework through sharing the same N7‐containing btx ligands.