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Alkaline Earth Metal Salts of 5,5′‐Bistetrazole – from Academical Interest to Practical Application
Author(s) -
Fischer Niko,
Klapötke Thomas M.,
Peters Kristina,
Rusan Magdalena,
Stierstorfer Jörg
Publication year - 2011
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201100263
Subject(s) - differential scanning calorimetry , alkaline earth metal , raman spectroscopy , chemistry , salt (chemistry) , elemental analysis , infrared spectroscopy , metal , crystallography , analytical chemistry (journal) , inorganic chemistry , nuclear chemistry , organic chemistry , physics , optics , thermodynamics
The alkaline earth metal salts of 5,5′‐BT, [Be(H 2 O) 4 ](5,5′‐BT) · H 2 O ( 1 ), [Mg(H 2 O) 6 (5,5′‐BT) · 3H 2 O ( 2 ), [Ca(H 2 O) 4 (5,5′‐BT)] · H 2 O ( 3 ), [Sr(H 2 O) 4 (5,5′‐BT)] · 2DMF ( 4 ), and [Ba(H 2 O) 4 (5,5′‐BT)] ( 5 ) were fully characterized by low temperature X‐ray diffraction, vibrational (IR, Raman) and NMR spectroscopy, elemental analysis and differential scanning calorimetry (DSC). A detailed description of the crystal structures is given. In addition, the potential use of 4 and 5 in coloring pyrotechnical compositions was investigated.