The Crystal and Molecular Structure of  γ ‐P 4 S 6 | Zendy

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The Crystal and Molecular Structure of γ ‐P 4 S 6

Author(s) -

Rödl Thomas,

Pfitzner Arno

Publication year - 2011

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201100216

Subject(s) - crystallography , crystal structure , molecule , diffraction , crystal (programming language) , symmetry (geometry) , group (periodic table) , x ray crystallography , space (punctuation) , chemistry , topology (electrical circuits) , materials science , physics , combinatorics , mathematics , geometry , optics , computer science , programming language , organic chemistry , operating system

The crystal and molecular structure of γ ‐P 4 S 6 was determined from single‐crystal X‐ray diffraction. It crystallizes monoclinically in the space group P 2 1 / m (No. 11) with a = 6.627(3) Å, b = 10.504(7) Å, c = 6.878(3) Å, β = 90.18(4)°, V = 478.8(4) Å 3 , and Z = 2. The structure consists of cage‐like P 4 S 6 molecules with C S symmetry arranged with the topology of a cubic close packing.

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