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The Crystal and Molecular Structure of γ ‐P 4 S 6
Author(s) -
Rödl Thomas,
Pfitzner Arno
Publication year - 2011
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201100216
Subject(s) - crystallography , crystal structure , molecule , diffraction , crystal (programming language) , symmetry (geometry) , group (periodic table) , x ray crystallography , space (punctuation) , chemistry , topology (electrical circuits) , materials science , physics , combinatorics , mathematics , geometry , optics , computer science , programming language , organic chemistry , operating system
The crystal and molecular structure of γ ‐P 4 S 6 was determined from single‐crystal X‐ray diffraction. It crystallizes monoclinically in the space group P 2 1 / m (No. 11) with a = 6.627(3) Å, b = 10.504(7) Å, c = 6.878(3) Å, β = 90.18(4)°, V = 478.8(4) Å 3 , and Z = 2. The structure consists of cage‐like P 4 S 6 molecules with C S symmetry arranged with the topology of a cubic close packing.