Premium
Hydrazinium Nitriminotetrazolates
Author(s) -
Fischer Niko,
Klapötke Thomas M.,
Stierstorfer Jörg
Publication year - 2011
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201100149
Subject(s) - detonation , detonation velocity , raman spectroscopy , hydrazine (antidepressant) , elemental analysis , explosive material , single crystal , diffraction , spectroscopy , crystal (programming language) , standard enthalpy of formation , materials science , infrared spectroscopy , chemistry , analytical chemistry (journal) , crystallography , inorganic chemistry , physics , optics , organic chemistry , programming language , chromatography , quantum mechanics , computer science
Hydrazinium 5‐nitrimino‐1 H ‐tetrazolate ( 1 ) and dihydrazinium nitriminotetrazolate monohydrate ( 2 ) were synthesized by the reaction of hydrazine with 5‐nitriminotetrazole. The energetic compounds 1 and 2 were characterized by single‐crystal X‐ray diffraction (only 2 ), NMR spectroscopy, IR‐ and Raman spectroscopy as well as DSC measurements. The sensitivities towards impact, friction and electrical discharge were determined. In addition, several detonation parameters (e.g. heat of explosion, detonation velocity) were computed by the EXPLO5 computer code based on calculated (CBS‐4M) heats of formation and X‐ray densities.