Syntheses and Structures of Nitridorhenium(V) and Nitridotechnetium(V) Complexes with  N , N ‐[(Dialkylamino)(thiocarbonyl)]‐ N ′‐(2‐hydroxyphenyl)benzamidines | Zendy

Nguyen Hung Huy | Zendy; Trieu Thi Nguyet | Zendy; Abram Ulrich | Zendy

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Syntheses and Structures of Nitridorhenium(V) and Nitridotechnetium(V) Complexes with N , N ‐[(Dialkylamino)(thiocarbonyl)]‐ N ′‐(2‐hydroxyphenyl)benzamidines

Author(s) -

Nguyen Hung Huy,

Trieu Thi Nguyet,

Abram Ulrich

Publication year - 2011

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201100134

Subject(s) - benzamidine , deprotonation , chemistry , ligand (biochemistry) , stereochemistry , medicinal chemistry , crystallography , ion , organic chemistry , receptor , biochemistry , enzyme

[ M NCl 2 (PPh 3 ) 2 ] complexes ( M = Re, Tc) react with N ‐[(dialkylamino)(thiocarbonyl)]‐ N ′‐(2‐hydroxyphenyl)benzamidines (H 2 L 1 ) with formation of neutral, five‐coordinate nitrido complexes of the composition [ M N(L 1 )(PPh 3 )]. The products have distorted square‐pyramidal coordination spheres with each a tridentate, double‐deprotonated benzamidine and a PPh 3 ligand in their basal planes.

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