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Syntheses, Crystal Structures, and Luminescence Properties of Dinuclear Metal (Ag + and Cu + ) Complexes with the Ligand 2‐MTPP [2‐MTPP = 2‐(Methylthio)‐4‐(pyridin‐2‐yl)pyrimidine]
Author(s) -
Zhu HaiBin,
Zhang ShuYing,
Lu Xin,
Yang WenNa,
Gou ShaoHua,
Chen Jing
Publication year - 2011
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201100124
Subject(s) - luminescence , ligand (biochemistry) , chemistry , pyrimidine , crystallography , metal , stereochemistry , crystal structure , ion , photochemistry , medicinal chemistry , materials science , receptor , organic chemistry , biochemistry , optoelectronics
Abstract Reactions of the ligand 2 ‐ MTPP [2‐MTPP = 2‐(methylthio)‐4‐(pyridin‐2‐yl)pyrimidine] with AgNO 3 and CuI produced dinuclear silver(I) ( 1 ) and copper(I) ( 2 ) complexes, respectively. Both complexes adopt a chair‐like structure in which two 2 ‐ MTPP ligands and two metal ions are joined together through M –N and M –S coordination bonds. The luminescence properties of both complexes were investigated in solid state at room temperature.