Synthesis, Crystal Structure, and Properties of the 3D Porous Framework [Zn(INAIP)]·DMA·H 2 O | Zendy

Chen ManSheng | Zendy; Tan XiongWen | Zendy; Zhang ChunHua | Zendy; Kuang DaiZhi | Zendy

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Synthesis, Crystal Structure, and Properties of the 3D Porous Framework [Zn(INAIP)]·DMA·H 2 O

Author(s) -

Chen ManSheng,

Tan XiongWen,

Zhang ChunHua,

Kuang DaiZhi

Publication year - 2011

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201100082

Subject(s) - dimethylacetamide , thermogravimetric analysis , rutile , porosity , materials science , adsorption , molecule , solvent , diffraction , powder diffraction , crystallography , single crystal , chemical engineering , topology (electrical circuits) , chemistry , organic chemistry , composite material , optics , physics , mathematics , combinatorics , engineering

A new three‐dimensional (3D) porous framework [Zn(INAIP)] · DMA · H 2 O ( 1 ) [INAIP = 5‐(isonicotinamido)isophthalate, DMA = N , N ′‐dimethylacetamide] was synthesized by solvothermal methods and characterized by single‐crystal and powder X‐ray diffraction, as well as thermogravimetric analysis. The results of X‐ray diffraction analyses revealed that complex 1 has an unusual 3D architecture with the (3,6)‐connected rutile ( rtl ) topology. The adsorption behavior shows that compound 1 exhibits selective adsorptions of CO 2 over N 2 after the removal of the solvent molecules within the pores.

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