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A Zigzag‐Shaped Yb 4 Cluster Bridged by Pyridine‐2,6‐dimethanol
Author(s) -
Yang PeiPei
Publication year - 2011
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201100069
Subject(s) - zigzag , cluster (spacecraft) , crystallography , pyridine , materials science , core (optical fiber) , chemistry , stereochemistry , geometry , organic chemistry , composite material , mathematics , computer science , programming language
A homometallic lanthanide tetranuclear cluster, namely [Yb 4 (pdmH) 2 (pdm) 4 (PhCO 2 ) 2 (PhCO 2 H) 2 (H 2 O) 2 ] · PhCO 2 H · 0.25MeOH ( 1 ) (pdmH 2 = pyridine‐2,6‐dimethanol) was prepared and structurally characterized. Single‐crystal X‐ray analysis revealed that complex 1 has a tetranuclear core with a zigzag arrangement. Magnetic properties of complex 1 were also investigated.