A Zigzag‐Shaped Yb 4  Cluster Bridged by Pyridine‐2,6‐dimethanol | Zendy

Yang PeiPei | Zendy

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A Zigzag‐Shaped Yb 4 Cluster Bridged by Pyridine‐2,6‐dimethanol

Author(s) -

Yang PeiPei

Publication year - 2011

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201100069

Subject(s) - zigzag , cluster (spacecraft) , crystallography , pyridine , materials science , core (optical fiber) , chemistry , stereochemistry , geometry , organic chemistry , composite material , mathematics , computer science , programming language

A homometallic lanthanide tetranuclear cluster, namely [Yb 4 (pdmH) 2 (pdm) 4 (PhCO 2 ) 2 (PhCO 2 H) 2 (H 2 O) 2 ] · PhCO 2 H · 0.25MeOH ( 1 ) (pdmH 2 = pyridine‐2,6‐dimethanol) was prepared and structurally characterized. Single‐crystal X‐ray analysis revealed that complex 1 has a tetranuclear core with a zigzag arrangement. Magnetic properties of complex 1 were also investigated.

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