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Pentamethylcyclopentadienyl(η 6 ‐cyclooctatrienyl)ruthenium Tetrachlorozincate, [RuCp*(η 6 ‐C 8 H 10 )] 2 ZnCl 4
Author(s) -
Bruce Michael I.,
Joly Damien,
Skelton Brian W.,
White Allan H.
Publication year - 2011
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201000447
Subject(s) - chemistry , ruthenium , ring (chemistry) , medicinal chemistry , crystal (programming language) , component (thermodynamics) , crystallography , organic chemistry , catalysis , thermodynamics , physics , computer science , programming language
The crystal and molecular structures of the title compound, the first for a complex of the type [RuCp*(η 6 ‐C 8 ‐ring)] + , is presented, the material being obtained serendipitously from a reaction between RuCl(cod)Cp* and 1‐ferrocenylbuta‐1,3‐diyne in the presence of ZnCl 2 . (2.21 Å) is appreciably longer than in RuCp* 2 (2.18 Å) and similar to the value for the Ru‐η 6 component (2.22 Å).
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