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Crystal and Molecular Structure of the trans ‐Hyponitrite Compound Ph 3 Sn(μ‐ONNO)SnPh 3
Author(s) -
Mayer Tobias,
Beck Wolfgang,
Böttcher HansChristian
Publication year - 2011
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201000444
Subject(s) - triclinic crystal system , benzene , crystal structure , crystallography , chemistry , bar (unit) , stereochemistry , crystal (programming language) , x ray crystallography , diffraction , physics , organic chemistry , optics , meteorology , computer science , programming language
The trans ‐hyponitrite compound Ph 3 Sn(μ‐ONNO)SnPh 3 ( 1 ) was revisited by NMR spectroscopy and the crystal and molecular structure was elucidated by X‐ray diffraction. Compound 1 crystallizes from benzene in the triclinic space group P $\bar{1}$ with a = 10.9674(2), b = 18.2786(2), c = 18.4592(2) Å; α = 115.979(1), β = 102.851(1), γ = 99.032(1)°; V = 3103.60(9) Å 3 ; Z = 4, ρ = 1.627 g · cm –3 , T = 173(2) K.