Structural Studies of Several Ru 3  and Ru 4  Carbonyl Clusters | Zendy

Bruce Michael I. | Zendy; Humphrey Paul A. | Zendy; Skelton Brian W. | Zendy; White Allan H. | Zendy

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Structural Studies of Several Ru 3 and Ru 4 Carbonyl Clusters

Author(s) -

Bruce Michael I.,

Humphrey Paul A.,

Skelton Brian W.,

White Allan H.

Publication year - 2011

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201000436

Subject(s) - metal carbonyl , chemistry , crystal structure , carbon fibers , crystallography , stereochemistry , materials science , organic chemistry , metal , composite number , composite material

The preparation, characterisation and single‐crystal XRD molecular structure determinations of the three Ru 3 carbonyl clusters attached to carbon ligands, Ru 3 (μ‐H) 3 (μ 3 ‐CBr)(CO) 9 ( 1 ), Ru 3 (μ‐H)(μ‐dppm){μ‐C(OMe)}(CO) 8 ( 2 ) and AuRu 3 (μ‐H) 2 (μ 3 ‐C=C=CHPh)(CO) 10 ( 3 ) are reported, together with the structures of the tetranuclear hydrido‐carbonyls Ru 4 (μ‐H) 4–2 x (CO) 11+ x (PPh 3 ) ( x = 0 4 , 1 5 ).

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