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Structural Studies of Several Ru 3 and Ru 4 Carbonyl Clusters
Author(s) -
Bruce Michael I.,
Humphrey Paul A.,
Skelton Brian W.,
White Allan H.
Publication year - 2011
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201000436
Subject(s) - metal carbonyl , chemistry , crystal structure , carbon fibers , crystallography , stereochemistry , materials science , organic chemistry , metal , composite number , composite material
The preparation, characterisation and single‐crystal XRD molecular structure determinations of the three Ru 3 carbonyl clusters attached to carbon ligands, Ru 3 (μ‐H) 3 (μ 3 ‐CBr)(CO) 9 ( 1 ), Ru 3 (μ‐H)(μ‐dppm){μ‐C(OMe)}(CO) 8 ( 2 ) and AuRu 3 (μ‐H) 2 (μ 3 ‐C=C=CHPh)(CO) 10 ( 3 ) are reported, together with the structures of the tetranuclear hydrido‐carbonyls Ru 4 (μ‐H) 4–2 x (CO) 11+ x (PPh 3 ) ( x = 0 4 , 1 5 ).