The Inverse Perovskite (Ca 2 EuN  x  )Sn: A Rare Example for a Homogeneously Mixed‐Valent Compound? | Zendy

Gäbler Frank | Zendy; Bräunling Daniel | Zendy; Schnelle Walter | Zendy; Schellenberg Inga | Zendy; Pöttgen Rainer | Zendy; Niewa Rainer | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

The Inverse Perovskite (Ca 2 EuN x )Sn: A Rare Example for a Homogeneously Mixed‐Valent Compound?

Author(s) -

Gäbler Frank,

Bräunling Daniel,

Schnelle Walter,

Schellenberg Inga,

Pöttgen Rainer,

Niewa Rainer

Publication year - 2011

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201000416

Subject(s) - europium , perovskite (structure) , mössbauer spectroscopy , electrical resistivity and conductivity , x ray absorption spectroscopy , magnetic susceptibility , crystallography , spectroscopy , doping , x ray crystallography , chemistry , analytical chemistry (journal) , diffraction , absorption spectroscopy , mössbauer effect , materials science , inorganic chemistry , ion , physics , optoelectronics , quantum mechanics , optics , organic chemistry , chromatography

The cubic Perovskite (Ca 2 EuN 0.75 )Sn was synthesized in a solid state reaction from EuN, Ca, and Sn. Nitrogen deficiency and Ca/Eu disorder is in agreement with results from chemical analysis, X‐ray diffraction, and Mössbauer spectroscopy. Magnetic susceptibility measurements as well as Mössbauer and X‐ray absorption spectroscopy indicate a mixed‐valent situation with di‐ and trivalent europium, apparently situated together with calcium on one crystallographic site. According to electrical resistivity measurements the title compound represents a heavily doped semiconductor.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research